First, you need some basic knowledge about the ASME Code applications. You may start with the book "The ASME Code Simplified", follow this link:
http://books.google.com/books?id=kvPbbJ ... ME#PPP1,M1.
Second, you need to decide on what stamp you need. Here are examples of ASME certificate scopes:
A-2. Assembly of power boilers at the above location and field sites controlled by the above location.
PP-2. Fabrication and assembly of pressure piping at the above location and field sites controlled by the above location
S-2. Manufacture and assembly of power boilers at the above location and field sites controlled by the above location.
Remember: PP certificate is for boiler proper piping only. If you have A or S certificate you do not need PP certificate.
Important: you need to select the Authorized Inspection Agency. Your AI and AIS will be your best consultants.
Good Luck.