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I'm not familiar with API 620 either, but I can make a suggestion as to internal/external. ASME is normally very concerned with fatigue failures, which only happens to material under tension. Heads with pressure on the convex side essentially discount fatigue failure and assume a joint efficiency of 1. That can result in a lower required thickness than for internal pressure if not much NDE is done, or castings are used, etc.
But once you go over 60 degrees and ASME forces you to assume a flat head, there's not much difference between internal or external pressure. You must use a joint efficiency factor, although it may be hidden inside the C factor for a corner joint. Maybe API 620 is less concerned about fatigue failure, being a low-pressure code, and allows a high joint efficiency even at 75 degrees? Just a guess.
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