Quote:
Gonzaga wrote:
"Another point to consider is: Is it required to PWHT tubes to tubesheet welds in L service? or it is exempted per Fig UCS-56 (for PNo.1) Note (2)(c)(2)? .."
PWHT acc. to UCS-56 and UW-2(a) are applicable only for carbon and low alloy steel. For the tube-to-tubsheet welding of the above mentioned vessel is PWHT not required, because they are type 304 steel [see table UHA-32, P-No. 8].
If austenic steels type 304 was heat treated at temperature and times as required for carbon or low alloy steels, they are sensible for intergranular corrosion. That means it is not the right solution for the manufacturing sequence that this austenitic steel will be heat treated with the cabon steel portion of the vessel. Especially for a chemical pressure vessel this is not acceptable regardless to code requiremnets.
Please see also UHA-102 with reference to ASME IID, A-320 and UHA-105 with reference to ASME IID, A-350
Code:
ASME IID
A-320 INTERGRANULAR CORROSION
When austenitic steels are held for a sufficient time
between 425°C and 870°C, chromium carbide tends to
precipitate preferentially at austenite grain boundaries.
This type of precipitation is referred to as sensitization.
Intergranular corrosion takes place when a sensitized
material is exposed to a sufficiently strong corrosive
medium for a long enough time.
Methods for combating intergranular corrosion include
the following:
(a) An anneal at 1 010°C to 1 120°C followed by rapid
cooling through the sensitization range. Subsequent operation
of a vessel in the sensitization range may resensitize
the material.
(b) Stabilizing with columbium, titanium, or tantalum.
These elements have a strong affinity for carbon and, in
sufficient quantities, prevent the precipitation of chromium
carbides.
(c) Use of types of steel having a low enough carbon
content that the chromium depletion at the grain boundaries
is kept within safe limits.
A-350 HEAT TREATMENT OF AUSTENITIC CHROMIUM–NICKEL STEELS
In recognition of controversial opinion relative to the
effects of postweld heat treatment of austenitic stainless
steels, mandatory requirements for such have been omitted.
Service experience is too limited to permit comparison
between the relative safety of as-welded and postweld
heat treated austenitic steel weldments, particularly in
thick sections. It is recognized that the stability of austenitic
steels and their optimum behavior in service are
influenced by the mechanical and thermal treatment they
have received; however, it is a basic principle that the
Code rules are intended to provide minimum safety
requirements for new construction, not to cover deterioration
which may occur in service as a result of corrosion,
instability of the material, or unusual operating conditions
such as fatigue or shock loading.
Where maximum corrosion resistance is required, it is
advisable to heat treat in such a fashion as to place all
chromium carbides in solution. For such service it is
recommended that the following procedure be followed:
hold the vessel within the solution temperature range
prescribed by the governing material specifications for
not less than 1 hr /25.4 mm of thickness. Quench all
parts of the vessel uniformly and as rapidly as possible.
Material not stabilized with columbium or titanium
should be cooled through the range from 925°C to 540°C
in not more than 3 min. The rapid cooling should be
continued to below 425°C. Slower cooling rates may be
just as satisfactory for some compositions of the material
and conditions of service.
A possibility to avoid the heat treatment of the austenitic steel is:
-buttering of groove face of the carbon steel portion with Ni-base alloy
-PWHT as required for the carbon steel portion (including the buttering)
-welding of the SS-portion to the buttered groove face of the cabon steel portion - and PWHT is not required