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What does this sentence meant for, "The maximum pressure in normal operating position at the top."
This point accounts for the additional pressure due to the liquid level that may exist in the vessel during operation. The pressure components below the liquid level will be subjected to the pressure at the top of the vessel plus the additional pressure due to the hydrostatic head of the operating liquid.
For example, let's say that the pressure chamber's MAWP is 100 psi as governed by the bottom head, and that there is no operating liquid. Now if the vessel operation is reconfigured such that there is an operating liquid and the pressure on the bottom head due to this liquid is 12 psi, then the pressure chamber MAWP must be reduced: 100 - 12 = 88 psi. Otherwise, if you consider the 100 psi original MAWP + 12 psi liquid pressure the head would be overstressed.
I have actually been asked about this a number of times. A designer will design a vessel for a particular pressure that is same as the pressure rating for, say, a Class 300, etc, flange. Then they add a liquid level and the flange is no longer "good" and they wonder why. This is because the pressure that the flange now is subjected to is greater than its pressure rating.