[quote]what's the category for this kind joint? category D?[/quote]
YES, it is a Category D butt weld joint
[quote]It is a butt weld joint, so 100% RT is required as per UW11a(2)?[/quote]
YES, full radiography is required on the Category D butt weld joint.
[quote]if it is, how to perform the RT.[/quote]
You perform the RT the same way as you would RT any butt weld joints. If you cannot obtain an interpretable radiograph, you could invoke Code Case 2235-9 (Ultrasonic Examination in Lieu of Radiography) if it is acceptable to your Jurisdiction and Client/Owner...
http://www.sonotronndt.com/pdf%5CASME.pdf